Extractive Resolution of racemic mandelic acid through a bulk liquid membrane containing binary chiral carrier
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منابع مشابه
Extractive Resolution of Racemic Mandelic Acid through a Bulk Liquid Membrane Containing Binary Chiral Carrier
Um método empregando “bulk liquid membrane” (BLM) e o complexo ácido di(2-etilhexil) fosfórico (D2EHPA) e ácido O,O’-dibenzoil-(2R, 3R)-tartárico (L-(-)-DBTA) foi desenvolvido para a separação por extração do ácido mandélico racêmico (rac MA). Os efeitos de tempo de resolução, concentração de D2EHPA na fase orgânica, concentração de rac MA na fase doadora, velocidade de agitação e temperatura s...
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The kinetics of the potassium thiocyanate transport mediated by dicyclohexyl-18-crown-6 (L) through a bulk liquid membrane is studied experimentally and theoretically. The proposed model is based on the assumption of a pure diffusion of the complex salt [K·L]+SCN¯ through the liquid membrane stagnant films at the interfaces. It illustrates the ...
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This paper deals with the resolution of racemic -cyclohexyl-mandelic acid containing copper(II) N-dodecyl-(L)-hydroxyproline (CuN2) as a chiral carrier across hollow fiber supported liquid membrane. A mathematical model of transport and resolution of chiral compounds was deduced, the observed partition coefficient between the feed phase and the membrane phase, the stripping phase and the membra...
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the kinetics of the potassium thiocyanate transport mediated by dicyclohexyl-18-crown-6 (l) through a bulk liquid membrane is studied experimentally and theoretically. the proposed model is based on the assumption of a pure diffusion of the complex salt [k·l]+scn¯ through the liquid membrane stagnant films at the interfaces. it illustrates the connection between liquid-liquid extraction equilib...
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Este artigo trata da separação enantiomérica do ácido α-cicloexilmandélico contendo cobre(II) N-dodecil-(L)-hidroxiprolina (CuN 2 ) como um carregador quiral, usando uma membrana líquida suportada em fibra oca. Um modelo matemático de transporte e separação enantiomérica de compostos quirais foi deduzido; o coeficiente de partição observado entre a fase de alimentação e a membrana, a fase de el...
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ژورنال
عنوان ژورنال: Journal of the Brazilian Chemical Society
سال: 2009
ISSN: 0103-5053
DOI: 10.1590/s0103-50532009000800016